No, Halle Berry did not appear with Will Smith and Tommy Lee Jones in Men of Black 2. See full cast and crew here.
Halle Berry is famously known instead for playing Storm in the X-Men film series. She debuted as Storm in 2000’s X-Men as one of Professor Xavier’s original students and a member of the main X-Men team. She continued to play a major role in X2: X-Men United and X-Men: The Last Stand.
See Halle Berry filmography on IMDb.
Before becoming a successful Hollywood actress, Halle Berry was a beauty pageant runner-up. Read more about her beauty and talent, at Biography.com.
Of interest, Mental Floss shares 15 Out-of-This-World Facts About Men in Black.